Photocatalytic mineralization of hydroperfluorocarboxylic acids with heteropolyacid H₄SiW₁₂O₄₀ in water

The decomposition of hydroperfluorocarboxylic acids [H-PFCAs; HC_nF_2nCOOH (n = 4 and 6)] induced by heteropolyacid photocatalyst H₄SiW₁₂O₄₀ in water was investigated, and the results are compared with the results for the corresponding perfluorocarboxylic acids (PFCAs; C_nF_2n+1COOH). This is the first report on the photochemical decomposition of H-PFCAs, which are being developed as alternative surfactants to environmentally persistent and bioaccumulative PFCAs. H-PFCAs were not decomposed by irradiation with UV-Visible light (>290 nm) in the absence of H₄SiW₁₂O₄₀. In contrast, UV-Visible light irradiation of H-PFCAs in the presence of H₄SiW₁₂O₄₀ efficiently decomposed H-PFCAs to F⁻ and CO₂. The decomposition reactions showed pseudo-first-order kinetics, and the decomposition rate constants were 1.8-2.5 times higher than those for the corresponding PFCAs. The reaction mechanism can be explained by elimination of H⁺ from the ω-H atom of the H-PFCAs by the excited catalyst, followed by formation of perfluorodicarboxylic acids.     

Resource management for sustainable development: a community- and GIS-based approach

A combined approach utilizing GIS, Participatory Rural Appraisal (PRA) and Focus Group Discussion (FGD) has been developed for resource mapping in a rural poverty-prone area of Bangladesh. This model integrated GIS and participatory tools to include the voices of the stakeholders in assessing available resources and needs. The resource mapping framework, developed using PRA with local community people and community gatekeepers, was aimed at sustainable resource management, and ArcView GIS was used to digitize the resource maps as a Decision Support System (DSS). A detailed assessment and analysis of the quality, quantity and physical status of resources was first mapped in the field and then digitized using GIS. FGD-based interaction with community people at each union in a subdistrict of Bangladesh revealed stakeholders’ opinions on land and water body management. The present paper demonstrates the power of this model as a policy-making tool for sustainable development and poverty eradication. It also recognized the need for collaboration between interdisciplinary policy planners and researchers to develop and implement a policy on agricultural resource management for poverty-prone areas.     

Environmental Kuznets Curve: the case of Bangladesh for waste emission and suspended particulate matter

Economists have shown the empirical relationships between the economic growth of a nation and its environmental quality using the hypothesis of the Environmental Kuznets Curve (EKC). To understand the EKC phenomena, a study of the literature was undertaken. As waste, waste emission, and suspended particulate matter (SPM) are the active agents of environmental degradation, the study focused on those agents for EKC consideration. Through understanding the different EKC trajectories, an attempt was made to relate the economic development of Bangladesh to the EKC. It is shown that the EKCs for waste, emissions from waste, and SPM follow the conventional EKC trajectory with a turning point related to higher income per capita in most cases. The type of economic policy that Bangladesh should follow to deal with the pollutants and their sources is also shown. The study recommends creating a tunnel in the EKC to lower the turning point in Bangladesh. The study is likely to help stimulate policy development in Bangladesh.     

Factors influencing the sustained participation of farmers in participatory forestry: a case study in central Sal forests in Bangladesh

Wide acceptance of sustainable development as a concept and as the goal of forest management has shifted forest management policies from a traditional to a people-oriented approach. Consequently, with its multiple new objectives, forest management has become more complex and an information gap exits between what is known and what is utilized, which hinders the sustained participation of farmers. This gap arose mainly due to an interrupted flow of information. With participatory forestry, the information flow requires a broad approach that goes beyond the forest ecosystem and includes the different stakeholders. Thus in participatory forest management strategies, policymakers, planners and project designers need to incorporate all relevant information within the context of the dynamic interaction between stakeholders and the forest environment. They should understand the impact of factors such as management policies, economics and conflicts on the sustained participation of farmers. This study aimed to use primary cross-sectional data to identify the factors that might influence the sustained participation of farmers in participatory forestry. Using stratified random sampling, 581 participants were selected to take part in this study, and data were collected through a structured questionnaire by interviewing the selected participants. To identify the dominant factors necessary for the sustained participation of farmers, logistic regression analyses were performed. The following results were observed: (a) sustained participation is positively and significantly correlated with (i) satisfaction of the participants with the tree species planted on their plots; (ii) confidence of the participants that their aspired benefits will be received; (iii) provision of training on different aspects of participatory forestry; (iv) contribution of participants' money to Tree Farming Funds. (b) The sustained participation of farmers is negatively and significantly correlated with the disruption of local peoples' interests through implementation of participatory forestry programs, and long delays in the harvesting of trees after completion of the contractual agreement period.     

Evidence of high organotrophic potentiality of bacteria in the deep ocean

The organotrophic potentiality of heterotrophic microorganisms 50 cm above the ocean floor (5,207 m depth) was measured in situ, at a station in the subarctic Pacific Ocean (44° N; 154° E). In certain enriched deep-sea samples incubated in situ, the microorganisms exhibited nearly the same organotrophic activity as those in the surface water layers. Rod-shaped barophilic bacteria (0.4 to 0.6 μ x 1.0 to 2.0 μ), which multiplied at a generation time of about 10 h, were responsible for this activity.     

Community attitudes toward forest conservation programs through collaborative protected area management in Bangladesh

The formulation of conservation policies with options for creating protected areas is significantly influenced by the social factors of the surrounding communities. Therefore, indigenous knowledge, attitudes and perceptions of the local communities need to be explored during the planning and implementation stages of conservation projects. A government-initiated experiment in co-management was conducted in the Rema-Kalenga Wildlife Sanctuary, Bangladesh. This paper analyzes the attitudes toward conservation by members of local communities living in and around the wildlife sanctuary. Training incentives on alternative income-generating (AIG) activities and allotment of agricultural lands were distributed among the Forest User Groups. It is of interest to policy makers and resource managers whether this technique leads to improved attitudes on the part of local people. Although there were different attitudes toward protected areas and conservation, overall, a favorable attitude of the respondents was observed. The opinions of respondents also varied based on factors such as village position, village dependency level on forest resources, ethnicity and gender. Increase in annual income resulting from the augmented skills by trainings on AIG activities and getting agricultural lands leased from the Forest Department contributed significantly to the variation in respondents’ conservation attitudes. It is suggested that eliminating inequity and inequality in incentive distribution, discovering and launching training on more need-based livelihood activities, and liberalizing the restriction of resource extraction from the protected area by fixing the harvesting limit would encourage the community to be more cordially and actively involved in the conservation efforts of the sanctuary.     

Influence of transportation and pumping on the properties of concrete with large amount of copper slag fine aggregate in actual construction of port and harbor structures

Journal of Material Cycles and Waste Management - Copper slag fine aggregate (CUS) is 30% denser than normal aggregate is an effective material for port and harbor structures demanding high-density...     

Major climate-change issues covered by the daily newspapers of Bangladesh

Communications research scholars, political scientists, and policy analysts have significantly recognized the role of news media in reporting and portraying public issues. Nowadays, climate change is an important global environmental concern for the world communities. Study on the media coverage of climate-change issues is vitally important to know the present situation of both the global and regional climate, as well as to assess the causes, mitigation and adaptation techniques, and its adverse impacts. This study demonstrates the coverage of newspapers in Bangladesh on climate change from May 2006 through June 2009 for the three most popular newspapers of Bangladesh, namely The Prothom Alo, The Daily Ittefaq, and The Daily Star. Natural disasters was the major climate-change issue that received the most coverage, along with agriculture, biodiversity, global warming, climate change, crime, water scarcity, food scarcity, politics, wetlands, tourisms, rivers, forestry and miscellaneous issues. Local communication concerned with climate-change issues was given preference in the coverage by the newspapers throughout the study period. The study will be useful for awareness-program formulation on climate-change mitigation and adaptation in Bangladesh.     

Explosion properties of highly concentrated ozone gas

The explosive self-decomposition characteristics of gaseous ozone with a concentration of up to almost 100 vol% were quantitatively investigated using a closed system with an electric spark device. The lower self-decomposition (explosion) limit for ozone diluted with oxygen at room temperature and atmospheric pressure was 10–11 vol%, and so ozone at more than 10–11 vol% will lead to an explosive chain decomposition reaction leading to its complete conversion to oxygen in a vessel. The lower explosion limit shifts to a higher concentration with a decrease in pressure. The limit was about 80 vol% under a reduced pressure of 10 Torr. We also confirmed that explosion trigger energy (minimum ignition energy) is strongly dependent on ozone concentration and pressure. For example, the minimum trigger energy for 15 vol% ozone at a pressure of 76 Torr (about 220 mJ) was more than 20-fold that at atmospheric pressure (about 10 mJ), and that for 13 vol% ozone (about 580 mJ) was approximately 30 times higher than that for 20 vol% (about 20 mJ) at the same pressure of 76 Torr. Moreover, the physical characteristics of the trigger energy sources (e.g. spark gap and electrode tip angle) leading to the decomposition (explosion) of ozone were investigated under various conditions.     

Comparison of photosynthetic responses to manganese toxicity of deciduous broad-leaved trees in northern Japan

The effects of manganese (Mn) toxicity on photosynthesis of four tree species in northern Japan representing different successional traits were examined. The four species are: Betula ermanii (Be) and Alnus hirsuta (Ah) representing two early successional species, Ulmus davidiana var. japonica (Ud) as the mid-successional species, and Acer mono (Am) as the late successional species. Seedlings were grown hydroponically in a solution containing nutrients and Mn of four concentrations (1, 10, 50, 100 mg litre(-1)) for 50 days. Gas exchange measurements indicate that in all species, Mn accumulation in leaves resulted in the decline of light-saturated net photosynthetic rate ai ambient CO(2) pressure (35 Pa, Pn(amb)) and at saturating (5%) CO(2) pressure (Pn(sat)), and of carboxylation efficiency but has little effect on the maximum efficiency of photochemistry. Sensitivity to elevated levels of Mn differed among species where the decline of Pn(amb) was much more modest in the two early successional species of Be and Ah than the mid- and late successional species of Ud and Am. The same trends were observed in both Pn(sat) and carboxylation efficiency. Based on these results, we suggest that early successional species (Betula ermanii and Alnus hirsuta) have greater tolerance for excess Mn in leaves than mid- and late successional species.